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Question: Using suitable examples briefly discuss any 4 methods of synthesizing organometallic compounds
Organometallic compounds are made up of organic parts, which include carbon atoms, and a metal core. Here are four methods used to synthesize them: 1. Transmetallation: This is the process where an organic group is transferred from a metal to another metal. Example: In the Labouré reaction, a Grignard reagent is reacted with a lithium halide to produce an organolithium compound. Such as C6H5MgCl + LiBr → C6H5Li + MgClBr 2. Metalation: This involves the addition of an organometallic metal directly to an organic compound by directly replacing a hydrogen atom. For instance, lithiation is a common metalation which involves the addition of metallic lithium to an organic compound for example in the production of methyllithium from methane and lithium metal: CH4 + 4 Li → CH3Li + LiH 3. Oxidative Addition: It involves the breaking of a bond within a molecule and then adding the pieces around the metal core. An example is the synthesis of organometallic compounds via oxidative addition of organic halides, such as methyl iodide with a metal complex of Nickel (Ni(PPh3)4 + CH3I → CH3NiI(PPh3)2). 4. Transmetalation Reaction: This is a process of transferring an organic group from a metal atom to another metal atom. A typical example of this method would be the synthesis of organoboron reagents from Grignard or organolithium reagents with a boron compound (3 R-Li + B(OR')3 → B(OR')3-3 R + 3 Li-OR'). These methods are commonly utilized by chemists due to the unique properties that organometallic compounds exhibit, such as being strong reducing agents and being capable of catalyzing various reactions.
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