Ask AI: INTRODUCTION KINETICS OF AQUATION OF PENTAAMMINECHLOROCOBALT(III) CHLORIDE [Co(NH3)5Cl] 2+ INCLUDE REFERENCES

Aquation refers to the substitution of water molecules in a complex ion. In the case of pentaamminechlorocobalt(III) chloride [Co(NH3)5Cl]Cl2, the chloride ion (Cl-) is being replaced by a water molecule (H2O) in the following manner: [Co(NH3)5Cl]Cl2 + H2O => [Co(NH3)5(H2O)](Cl)3 + Cl- Understanding the changes in the kinetics of this reaction requires a good grasp of the principles of inorganic chemistry. The reaction follows the first order kinetics where the disappearance of [Co(NH3)5Cl]2+ is proportional to its initial concentration. Also, the rate of reaction is observed to be temperature dependent implying the Arrhenius equation approach can be applicable to this system. References: 1. Basolo, F. & Pearson, R. G. (1967). Mechanisms of Inorganic Reactions. New York: Wiley. 2. Kaim, W. & Schwederski, B. (2013). Bioinorganic Chemistry - Inorganic elements in the chemistry of life: An introduction and guide. Chichester: Wiley. 3. Housecroft, C. E., & Sharpe, A. G. (2012). Inorganic Chemistry (4th ed.). Pearson Education. 4. Miessler, G. L., Fischer, P. J., & Tarr, D. A. (2014). Inorganic chemistry (5th ed.). Boston: Pearson. 5. A.Thompson, Spectrophotometric measurement of rate constants. J.Chem. Educ. 1964;41(6): 330. DOI: 10.1021/ed041p330. To understand more about the kinetics of this reaction, you can refer to these books and research articles. They provide a comprehensive account of the mechanisms of inorganic reactions along with illustrations for more complex ions like pentaamminechlorocobalt(III) chloride. However, for very detailed and technical information, you would need to refer to research articles specific to this topic. Remember, understanding the kinetics of a reaction can seem daunting, but with continuous effort and study, these principles can be mastered. I hope the information has been helpful.